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Technetium(VII) oxide : ウィキペディア英語版
Technetium(VII) oxide

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Technetium(VII) oxide is the chemical compound with the formula Tc2O7. This yellow volatile solid is a rare example of a molecular binary metal oxide, the other examples being RuO4, OsO4, and the unstable Mn2O7. It adopts a centrosymmetric corner-shared bi-tetrahedral structure in which the terminal and bridging Tc-O bonds are 167pm and 184 pm respectively and the Tc-O-Tc angle is 180°.
Technetium(VII) oxide is prepared by the oxidation of technetium at 450–500 °C:
:2 Tc + 3.5 O2 → Tc2O7
It is the anhydride of pertechnic acid and the precursor to sodium pertechnetate:
:Tc2O7 + 2 NaOH → 2 NaTcO4 + H2O
==References==



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